Harwood, known to young viewers for his role on shows such as Bear Behaving Badly, and as a co-host with Basil Brush, will become the 35th presenter on the magazine show.
He will replace Joel Defries, who leaves the flagship programme this week.
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Hide AdHarwood, from Blackpool, will take his seat alongside co-presenters Andy Akinwolere and Helen Skelton on 17 January.
He said: "Being a children's presenter is an ambition that I have already fulfilled but becoming a Blue Peter presenter is simply the icing on the cake. I cannot wait to start work with Andy and Helen, wear my badge on screen and tackle some exciting challenges."
Blue Peter, which is screened twice a week, was launched in 1958.