The 10 stamps feature the six actors who have played 007, as well as some of Q Branch's most well-known vehicles.
In keeping with the antics of the secret service agent, the Q Branch stamps include hidden features which can be revealed when using a UV light.
On Her Majesty's Secret Service (George Lazenby, 1969) and Goldfinger (Sean Connery, 1964).
Q Branch vehicles on the stamps are the Lotus Esprit S1 Submarine from The Spy Who Loved Me (1977), Little Nellie, the autogyro from You Only Live Twice (1967) the Bell-Textron Jet
Pack from Thunderball (1965) and the Aston Martin DB5, as seen in Skyfall (2012).
There are also specially designed limited-edition handstamps for pre-ordered first day covers and stamp souvenirs, with one image featuring the renowned quote: "We've been expecting you."
The stamps will be available from March 17, ahead of the new Bond film, No Time To Die, which is on release from April.