Gordon Cooper, 57, from Montrose died at the scene of the accident on the A9 north of Dunkeld in Perthshire on Thursday.
A 23-year-old man driving an empty tanker also suffered serious leg injuries in the smash at around 5.20am.
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Hide AdTayside Police said the articulated tanker, which was travelling north, collided with a McKay of Montrose lorry heading south.
The driver of a third lorry involved in the collision was not hurt.